In order to produce smaller amounts of oxygen, O2 from the air by adsorption of other gases can be separated. These air flows through molecular sieves. In this case, nitrogen and carbon dioxide are adsorbed and only O2 and argon pass through. This is used in O2 concentrator mainly used medically (oxygen for energy).
The development of O2 concentration in atmosphere is described in article Development of earth's atmosphere. The O2 allotrope O3 Ozone is present in atmosphere at low concentrations. In space, O2 is the third most abundant element after hydrogen and helium. The mass fraction of O2 is in solar system about 0.8% (this corresponds to an (atomic) number fraction of about 500 ppm).
Some oxygen-rich inorganic compounds such as potassium permanganate, potassium nitrate (saltpeter), potassium chlorate and potassium chromate enter upon heating or reaction with reducing agents from oxygen. A further possibility of producing O2 in laboratory, is the decomposition of hydrogen peroxide on platinum-plated nickel foil. Pure O2 can be obtained by electrolysis of 30% potassium hydroxide solution of nickel electrodes. It Hydrogen and O2 are separated.
Even in so-called main sequence stars like the sun plays a role in energy oxygen. In CNO cycle (CNO cycle) represents O2 is an intermediate of nuclear reaction in which proton capture by a 12C nucleus, which acts as a catalyst, a 4He nucleus (alpha particle) is produced. In extremely heavy stars occurs in late stage of their development to O2 burning, in which the O2 is used as nuclear fuel for reactions that lead to construction of even heavier nuclei.
With the discovery of O2 its meaning was not clear during combustion. The Frenchman Antoine Lavoisier found in his experiments that during combustion does not escape phlogiston, but O2 is bound. By weighing it demonstrated that a substance after combustion was not easier but harder. This was caused by the additional weight of ingested during the combustion process oxygen.
For O2 recovery after Claude process air by means of compressors to 5-6 bar is compressed, cooled and then removed by first filter of carbon dioxide, humidity, and other gases. The compressed air is cooled by flowing past gases from the process to a temperature near the boiling point. It is then expanded in turbines. A portion of energy used for compression can again be recovered. This is the method -. In contrast to Linde process, in which no energy is recovered - a lot more efficient.
The actual separation of nitrogen and O2 by distillation in two distillation columns with different pressures. The distillation is carried out in counter-current principle, that is by the condensation heat of evaporated gas flows upward, condensed liquid drips down. Since O2 has a higher boiling point than nitrogen, it condenses readily and collects at the bottom so, nitrogen at the top of column.
The separation takes place initially at 5-6 bar in so-called medium pressure column. The resulting oxygen-enriched liquid is then (pressure about 0.5 bar) further separated in low pressure column. Through the liquid O2 of low pressure column, gaseous nitrogen of high pressure column is passed. It liquefies this and heated with the votes condensation heat the liquid. The more volatile nitrogen is discharged and preferably remains purified liquid oxygen. This still contains the noble gases krypton and xenon, which are separated in a separate column.
The development of O2 concentration in atmosphere is described in article Development of earth's atmosphere. The O2 allotrope O3 Ozone is present in atmosphere at low concentrations. In space, O2 is the third most abundant element after hydrogen and helium. The mass fraction of O2 is in solar system about 0.8% (this corresponds to an (atomic) number fraction of about 500 ppm).
Some oxygen-rich inorganic compounds such as potassium permanganate, potassium nitrate (saltpeter), potassium chlorate and potassium chromate enter upon heating or reaction with reducing agents from oxygen. A further possibility of producing O2 in laboratory, is the decomposition of hydrogen peroxide on platinum-plated nickel foil. Pure O2 can be obtained by electrolysis of 30% potassium hydroxide solution of nickel electrodes. It Hydrogen and O2 are separated.
Even in so-called main sequence stars like the sun plays a role in energy oxygen. In CNO cycle (CNO cycle) represents O2 is an intermediate of nuclear reaction in which proton capture by a 12C nucleus, which acts as a catalyst, a 4He nucleus (alpha particle) is produced. In extremely heavy stars occurs in late stage of their development to O2 burning, in which the O2 is used as nuclear fuel for reactions that lead to construction of even heavier nuclei.
With the discovery of O2 its meaning was not clear during combustion. The Frenchman Antoine Lavoisier found in his experiments that during combustion does not escape phlogiston, but O2 is bound. By weighing it demonstrated that a substance after combustion was not easier but harder. This was caused by the additional weight of ingested during the combustion process oxygen.
For O2 recovery after Claude process air by means of compressors to 5-6 bar is compressed, cooled and then removed by first filter of carbon dioxide, humidity, and other gases. The compressed air is cooled by flowing past gases from the process to a temperature near the boiling point. It is then expanded in turbines. A portion of energy used for compression can again be recovered. This is the method -. In contrast to Linde process, in which no energy is recovered - a lot more efficient.
The actual separation of nitrogen and O2 by distillation in two distillation columns with different pressures. The distillation is carried out in counter-current principle, that is by the condensation heat of evaporated gas flows upward, condensed liquid drips down. Since O2 has a higher boiling point than nitrogen, it condenses readily and collects at the bottom so, nitrogen at the top of column.
The separation takes place initially at 5-6 bar in so-called medium pressure column. The resulting oxygen-enriched liquid is then (pressure about 0.5 bar) further separated in low pressure column. Through the liquid O2 of low pressure column, gaseous nitrogen of high pressure column is passed. It liquefies this and heated with the votes condensation heat the liquid. The more volatile nitrogen is discharged and preferably remains purified liquid oxygen. This still contains the noble gases krypton and xenon, which are separated in a separate column.
0 commentaires:
Enregistrer un commentaire